Is there a way to adapt the larger, 2.5 inch, mains in the block to the crankshaft with the Buick 215" 2.3 inch journals?
Over the years, that is one trick that I have never come across. It will be faster & cheaper to find a 4.0 crank or a 3.9 block.
Find a block from a 1995 discovery - even better if you can find one with a build date in the second half of 1995, and it'll have the tall caps in the block. It won't be cross-bolted, but thats an easy machining operation for an experienced shop. You WILL need to line-bore afterwards, but again, no real difficulty for the right shop.
More direct is better. Use 4L. crank=simpler,stronger and easier to balance. Good Luck, Art.